Abstract:
Historically ‘blue white’ fluorescent top coloured (D to F on the GIA colour grading scale) diamonds were once priced around 10% more than non fluorescent diamonds. Today D to F coloured blue fluorescent diamonds are usually discounted on wholesale markets. There are two main technical reasons why fluorescent diamonds would be discounted. The diamond’s body colour may have been ‘over-graded’ or its transparency may have been impaired.
There are also several possible “commercial” reasons why high coloured (D-F) blue fluorescent diamonds are often discounted. For example, they may be more difficult to sell. This article will review the complex and often contradictory history.
Introduction:
In the USA the Federal Trade Commission banned the use of the term ‘blue white’ in 1938. In 1993, Martin Rapaport added a fluorescence price guide to the Rapaport Diamond Report apparently as a response to events in Korea. In 1997 the Gemological Institute of America (GIA) published a survey in Gems & Gemology indicating that blue fluorescence was a benefit to diamond face up colour appearance. Shortly after, without declaration, the GIA Gem Trade Laboratory changed its grading illumination environment used to grade D-Z coloured diamonds to include more ultra violet light. Cape or yellowish diamonds that exhibit blue fluorescence are believed by many to receive higher colour grades than when ultra violet light was absent. The author solicited opinions while researching for this article concerning possible links between fluorescence and transparency from several respected lab directors and trade experts. Worryingly, the views differed widely. The history, pricing and related issues are discussed and some conclusions are offered.
What causes fluorescence?
Diamond is a very pure mineral. The most common impurity is a tiny amount of nitrogen (0.0001% to 0.01%) dispersed throughout the crystalline structure. When white light traverses a yellowish diamond some blue light is absorbed by the deformities in the crystal associated with the nitrogen causing a slight yellow appearance. Higher energy ‘light’ like x-rays or short wave ultra-violet can also cause the diamond to fluoresce and emit in the same frequency range that was previously only absorbed. Natural ultra-violet from daylight or even from some light globes is enough to make a fluorescent yellowish diamond appear whiter. Nitrogen can also occur in various ‘states’ with different electronic properties within a diamond so that it is possible for one D coloured non-fluorescent diamond to have 10 times more nitrogen than another that is K colour and fluorescent.
History
Background
After the discovery of diamonds in South Africa in 1867 some mines were renowned for producing a percentage of high colour diamonds that exhibited a bluish appearance in daylight as a result of their fluorescence. It came to be that these diamonds, especially those that were otherwise colourless, were termed ‘blue white’ and sold at a premium price.[1] However, human nature being what it is, some marketers of diamonds indulged in “bracket creep” and began to call diamonds of lower colours “blue white” in order to achieve a higher selling price and more profit. This led the United States of America Federal Trade Commission (FTC) to ban the use of the term ‘blue white’ on March 18, 1938 with the following resolution 23.14, (Trade Practice Rules for the Wholesale Jewellery Industry, Rule No. 6, p4:
23.14 Misuse of the term “blue white.” [2], [3]
It is unfair or deceptive to use the term "blue white" or any representation of similar meaning to describe any diamond that under normal, north daylight or its equivalent shows any color or any trace of any color other than blue or bluish.
Interestingly under this definition there are diamonds that could still be legally described as blue white, however it seems that the intention of the legislation has been observed, and, if anything, there has been an over-reaction. The FTC also made an attempt to define the type of lighting that might cause a diamond to fluoresce and appear ‘blue or bluish’. The detail however did not include terms such as ‘shaded’ or ‘indirect sunlight’ or make any reference to the time of day or atmospheric conditions. The quality of published industry and gemological opinion about the type of natural light that diamond colour ought to be judged or graded in, is poor and often contradictory, as can be noted in the following quotes.
Eric Bruton wrote in 1978 in ‘Diamonds’: [4]
“A very important consideration is that any fluorescence in the stone must be suppressed. A visible blue fluorescence can be caused in a yellowish diamond when ultra-violet light, which is invisible, falls on it. If the diamond is examined in sunlight, even reflected light, which contains ultra-violet light, the blue fluorescence will tend to cancel the yellowish body colour because the colours are nearly complementary, and the stone will appear to be whiter than it is. These stones are often mistakenly called ‘blue-white’. It is therefore important to grade stones in white light that is relatively free of ultra-violet and the orthodox method is to use daylight from a north-facing window in the northern hemisphere and from a south-facing one in the southern, i.e. with one’s back to the sun.”
“…but it must be remembered diamonds are rarely seen in such ideal conditions in wear because there is some ultra-violet in most daylight.”
“False White” Stone: If a stone has blue fluorescence and a tinted yellow body colour, the colours being complementary may cancel each other so that in some conditions the stone appears white. The experienced grader will recognize such stones because their colour grade appears to vary in different light intensities. A white light free of ultra-violet will disclose the true body colour and an ultra-violet lamp the fluorescence.”
Mr. Bruton is the only author who attempts to describe an orthodox and accepted colour grading environment of shaded daylight which has often been referred to as the environment that artificial light should mimic. However, Bruton then seems to contradict his own comments: “even reflected light, which contains ultraviolet light”….. “A white light free of ultra-violet will disclose the true body colour….” “but it must be remembered diamonds are rarely seen in such ideal conditions in wear because there is some ultra-violet in most daylight…..”
In 1986 Eddy Vleeschdrager wrote in ‘Hardness 10: Diamond’[5]
“A polished diamond is less valuable if its fluorescence is too high, for it will give the impression of having a better colour than it actually has in normal light conditions. The colour of a diamond has to be determined using a normalised artificial light source which corresponds to daylight. Because this light source simulates day light, it contains an amount of ultra-violet light. It is evident that the ultra-violet light will contribute to fluorescence.”
It is interesting to note the contradictions in Mr. Vleeschdrager’s quotes. A diamond should be less valuable if its colour is better in normal lighting? A diamond’s colour should be determined in ‘normalised’ artificial daylight which should contain an undefined amount of ultraviolet light. Did Mr. Vleeschdrager really intend to say that blue fluorescent diamonds will be overgraded in a normalised artificial light source, which by his own definition, should contain some unspecified content of ultra-violet light?
In 1980 Verena Pagel-Theisen in the 7th edition of ‘Diamond Grading ABC’[6] wrote:
“the body colour observed in normal light determines the colour grade of fluorescent diamonds” although there is no description in this book as to what constitutes ‘normal light’.
In the 9th edition of the same book, in 2001: [7]
“…the body colour observed in standardized light determines the fluorescent diamond’s colour grade.” ‘Normal light’ has become ‘standardized light’, but there is still no attempt to define a standard.
There is however an additional notation that “In the upper colour grades up to ‘white’, fluorescence means a reduced price because clear fluorescence can affect the transparency and clarity of the stone.” There is a recurrent theme in “Diamond Grading ABC” that fluorescence may affect the transparency of higher colour and clarity stones more than in the case of lower grades. If this is so then it has neither been discussed nor validated in the literature. In this writer’s diamond grading experience it does not appear to be the case. One can also only wonder why the term “clear fluorescence” was used in the same sentence as “transparency”
It becomes apparent from a review of the literature that there is no clear idea of what type of natural or artificial light should be used for diamond colour grading. It should also be noted that there have been no attempts by gemmologists or diamond grading laboratories to clearly define, describe or rate the levels of transparency that may be reduced in diamonds that fluoresce, or for that matter even in those that are inert. Transparency will be a recurring topic in this article.
‘KoreaGate’ In an interesting case study, prior to 1993, Korean retailers and consumers exhibited a preference and paid a premium for blue fluorescent diamonds. However a Korean current affairs TV program[8] in 1993 accused local Korean grading laboratories of over-grading the colour of fluorescent diamonds, suggesting for instance that “your G is really H”. Korean traders replaced many of the fluorescent diamonds they had sold earlier, becoming net sellers of fluorescent goods and buyers of non-fluorescent diamonds. This simultaneous dumping and demand of the different grades of goods seemingly contributed to an adjustment in the Rapaport Diamond Report price guide. A month or two later a chart appeared (Table 1) with price guides for blue fluorescent diamonds of different colours and clarities. This guide is still in place today, having had only some minor adjustments from time to time which presumably only reflect fluctuations in supply and demand.